(Z)-1-Chloro-1-[2-(2-nitrophenyl)hydrazinylidene]propan-2-one

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(Z)-1-Chloro-1-[2-(2-nitro­phen­yl)hydrazinyl­idene]propan-2-one

The title mol-ecule, C9H8ClN3O3, lies on a mirror plane. Intra-molecular N-H⋯O and N-H⋯Cl hydrogen bonds occur. One of the nitro O atoms is disordered (site occupancy ratio = 0.40:0.10).

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1-Chloro-1-[(Z)-2-phenyl­hydrazin-1-yl­idene]propan-2-one

The title compound, C(9)H(9)ClN(2)O, is close to planar (r.m.s. deviation for the non-H atoms = 0.0446 Å); it exists in a cis conformation with respect to the C=N double bond. In the crystal, the ketone O atom accepts both N-H⋯O and C-H⋯O hydrogen bonds, which leads to [010] infinite chains incorporating R(2) (1)(6) loops. The crystal structure also features a C-H⋯π inter-action.

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Ethyl (Z)-2-chloro-2-(2-phenyl­hydrazin-1-yl­idene)acetate

The title compound, C(10)H(11)ClN(2)O(2), features an almost planar C(ar)-N(H)-N=C(Cl) unit [torsion angle = 0.8 (1)° whose phenyl substituent is almost coplanar with it [dihedral angle = 2.8 (2)°]; this unit is slightly twisted with respect to the carboxyl -CO(2) fragment [dihedral angle = 10.3 (2)°]. In the crystal, the amino group acts as a hydrogen-bond donor to the carbonyl O atom of an ad...

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(Z)-3-(2-Amino­anilino)-1-phenyl­but-2-en-1-one

In the title compound, C16H16N2O, the phenyl and 2-amino-phenyl rings are almost perpendicular to one another, with a dihedral angle of 82.77 (8)°. There is an intra-molecular N-H⋯O hydrogen bond in the mol-ecule. In the crystal, mol-ecules are linked via N-H⋯O hydrogen bonds forming chains along [001]. There are also C-H⋯π inter-actions present, linking the chains to form a three-dimensional s...

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(Z)-3-(2-Methoxy­anilino)-1-phenyl­but-2-en-1-one

In the title compound, C(17)H(17)NO(2), the dihedral angle between the two benzene rings is 55.2 (2)°. The meth-oxy group is slightly twisted away from the aniline ring [dihedral angle = 10.3 (2)°]. An intra-molecular N-H⋯O inter-action is present. In the crystal, the mol-ecules are linked into a three-dimensional supra-molecular network through two sets of C-H⋯π inter-actions.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812049938